If something is twice as far away, it has to be twice as wide to have the same apparent size.
If it's 10x farther away, it needs to be 10x bigger.

The Sun is 4250 times farther away than GEO, so the object is 4250 times smaller than the Sun, so very close to 1000 km in circumference
That said, GEO wouldn't be a good place to permanently block the Sun. In GEO, a satellite is orbiting at the same speed as the Earth is rotating, which means that seen from the surface of the Earth, the satellite is motionless in the sky. The Sun is not motionless in the sky, so the occultation doesn't last very long (roughly the same time as a total solar eclipse, which just uses a slightly bigger sphere, slightly further out).
Another consideration is that ~1000km is just enough to make the Sun dark on a single point of the Earth. If you just drive a short distance away, the object will only cover parts of the Sun, and further away still, the Sun is shining like normal.
To block all of the Sun on all of the Earth, you would need something at least the size of the Earth
