Let's imagine we have finally developed buckytube rope. A couple hundred kilometers of rope, able to tug a 100-ton craft at 6g acceleration, in a package packable on said craft.
A near-earth asteroid is passing by. A craft is launched on a nearby flyby trajectory. When the flyby point approaches, the craft launches a "missile" - either an impactor one with a harpoon style hook, or some kind of net, or one that could create a loop... with the rope trailing. It catches the asteroid.
The craft unrolls the rope from a spool, while strongly braking the spool spin, so that the acceleration of the craft pulled by the rope is survivable for the crew/payload and doesn't break anything. This is until the spool stops or the whole rope unrolls (in which case it's allowed to fly loose with the asteroid, disengaging from the craft).
After the spool came to a standstill, the craft is anchored to the asteroid, having gained good several km/s essentially free.
What (beyond inventing a buckytube rope) obstacles could stand behind such a method of propulsion? Would heat dissipation of the brake be manageable? (say, some kind of ablator/sublimator, that's a one-off affair). Would that kind of propulsion make sense?