This question, as well as its answers and comments, highlights a lot of unsettling numerical coincidences where certain sums over twin primes ostensibly converge to all kinds of weird values, however most of them look fishy in some aspects such as convergence rate (see comments by Terry Tao). To shed more light on this, it would be helpful to obtain further values of these (partial) sums, still linear computation of these quickly becomes prohibitive.
A simpler related problem is to count the number $f(N)$ of twin primes in a range $[1, N]$ (basically, summing $1$ instead of other stuff over primes $(p, p + 2) \leq N$). The question is: which algorithms would allow us to compute this number in $O(N^{\alpha})$ time for $\alpha < 1$? What if we want to approximate $f(N)$ with (arbitrary) relative tolerance $\delta$?
Just for the reference point, there are quite a few sublinear algorithms for counting primes in a range; good places to look are here, here and here. It is not clear how much of these results can carry over to twin prime counting though.