Well, the best way to think about this is to know that we have
$$e^x = \sum_{n=0}^{\infty}\frac{x^n}{n!}.$$
We are essentially trying to take every third term in the following series, then negate every sixth and then remove the first term:
$$e^1 = \frac{1}{0!}+ \frac{1}{1!}+\frac{1}{2!}+\frac{1}{3!}+\frac{1}{4!}+\ldots.$$
The classic way to do this is to evaluate $e^x$ at various roots of unity and sum them together in a clever way to get the desired answer; for instance, simpler tasks like "take every second term" would be $\frac{1}2\left(e^{1}+e^{-1}\right)$. This is because the averages of $\frac{1}2(1^n + (-1)^n)$ is a sequence that is $0$ when $n$ is odd and $1$ when $n$ is even - so looking at power series gives that that sum is the even terms of the given sum.
Similarly, one can see that if $\gamma=e^{2\pi i/3}$ is a third root of unity, then the average $\frac{1}3(1+\gamma^n+\gamma^{2n})$ is $0$ whenever $n$ is not divisible by $3$ and $1$ otherwise. This leads us to see that $\frac{1}3(e^{1}+e^{\gamma}+e^{\gamma^2})$ is the sum of every third term in the series, because every other $x^n$ term cancels across the three different sums.
A little bit more finesse gives that the number you desire is given by negating the exponents (to get the desired alternation of sign), then subtracting the whole thing from $1$ to get the first sign correct and cancel the first term. Thus, your sum evaluates to
$$1-\frac{1}3\left(e^{-1}+e^{-\gamma}+e^{-\gamma^2}\right).$$
We can then write this in real terms by evaluating $\gamma = \frac{-1}2 + \frac{\sqrt{3}}2 i$ and noting that $e^{a+bi}+e^{a-bi}=2e^a\cos(b)$. This gives the sum as
$$1-\frac{1}3\left(\frac{1}e+2e^{1/2}\cos\left(\frac{\sqrt{3}}{2}\right)\right)$$
which agrees well with what you get when you evaluate the sum numerically.