From the XBee/XBeePro product manual page 24 (link to pdf):
Sleep Modes enable the RF module to enter states of low-power consumption when not in use. In order to enter Sleep Mode, one of the following conditions must be met (in addition to the module having a non-zero SM parameter value):
- Sleep_RQ (pin 9) is asserted and the module is in a pin sleep mode (SM = 1, 2, or 5)
- The module is idle (no data transmission or reception) for the amount of time defined by the ST (Time before Sleep) parameter. [NOTE: ST is only active when SM = 4-5.]
What is meant by "asserting a pin"?

RESET#signal makes more sense than to assert theRESET#pin (at least to me). It also avoids loaded words that might give the wrong idea if assertingRESET#involves driving it low (or not driving it high). – Alexios Jun 06 '12 at 22:31