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Basically, I read that nucleophilicity increases going down the periodic table within a particular group, due to polarizability, but basicity decreases down a group (or family) in the periodic table, because those atoms can stabilize a negative charge, making them good leaving groups. Don't these two points seem to contradict each other, since increasing nucleophilicity should increase basicity?

Mithoron
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Jay Dee
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  • https://chemistry.stackexchange.com/questions/20061/whats-the-difference-between-a-nucleophile-and-a-base – Mithoron May 31 '20 at 20:08

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