On my commuter bike I decided to rid myself of the small inner chain ring (which is almost never used) and front dérailleur (now redundant). However, I have come across an unusual problem. Whilst cycling the chain is coming off of the outer chain ring and falling onto the crank arm. This usually coincides with a shift of the rear dérailleur onto a smaller sprocket, although notably not onto the highest gearing - it has happened shifting from the 5th to 6th scrocket on the 12-27 cassette for example. Furthermore, I am not exerting abnormal force on the crank, just sitting and riding as normal. This just happens out of the blue and as you can imagine is quite disconcerting/dangerous.
I have considered and checked the following so far:
- Chain length - tension is good so no obvious problems there...
- Chain dirty - it most certainly is not, it has only seen 200 miles and its lubed up a treat ;-)
- Chain ring to cassette alignment - Hollowtech II BB and Ultegra 53T 6600 crank in 68mm shell, standard setup afaict, no obvious problems there...
- Lack of front-dérailleur - I removed this since there is only one chain ring - could this be a factor that prevented me noticing the problem before (surely not...)
- Chain ring worn - the chain ring looks in pretty good shape to me
I experimented briefly, turning the crank and applying a very slight outward pull (away from frame) on the chain and it promptly fell off onto the crank. Frankly, I was surprised how such a small misalignment could cause the chain the fall off...
My question: Has anyone else encountered this problem before?
Any comments on the things I have checked (why I may be mistaken in my assessment of the problem)?
Other possible causes I have missed would be gratefully received - this is spoiling an otherwise nice bike and I really do not want to go back to using the double crank configuration if possible.


Please consider continuing to update your question text as you resolve this problem. I'm looking forward to seeing how this gets resolved. Will share this with a mechanic friend of mine not on this network.
– Goodbye Stack Exchange Jul 18 '11 at 23:51