Thermal degradation of 3D printed ABS (and other plastics)

Question

The short version of my question is:

Are 3D printed parts made of ABS likely to survive for one year in an incubator at 80℃?

Please read on for more details.

I am printing some parts that will be used inside an incubator in a lab. They are likely to be used at 80℃ for at least a year, possibly even at higher temperatures than that. (But most likely under 100℃.)

We're currently using ABS for these parts. My question is whether 3D printed ABS will degrade under those conditions. (For example: will it become soft and slump; will it discolour; will it become brittle?) The parts clip together to form quite a big object, which is basically a rack holding a lot of glass vials, so it's important that it stays rigid.

I did find some papers on thermal degradation of ABS (for example this one looks quite comprehensive) but I don't have the experience to interpret them in terms of how my parts will behave practically. I'm also not sure if being 3D printed will make a difference.

If ABS is not suitable for this kind of application, are there other plastics that are? We're using the Zortrax M200, so our choices are the plastics listed here. I note that PCABS is listed as specifically being temperature resistant, so we might go with that - but we'd prefer ABS if it will work, since it comes in white rather than ivory (which is important for our application) and we have plenty of it available.

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update: we decided in the end that using ABS is too risky, so we went with PCABS and we'll just live with the yellowish colour. (We might paint it white.) It's currently in the oven on a test run, and if it doesn't fail in a few weeks we'll take the risk of running the year-long experiment with this material. However, we would still very greatly appreciate advice from anyone who has concrete knowledge or experience of this kind of situation.

Answer 1

To answer your question briefly: No, ABS will not survive for a duration of at least one year at 80-100°C.

If you look at the chart above (from Tiganis/Burn), you'll notice, that the blue line (ABS 90°C) is decreasing. I did an eyeball calculation of the graph and arrived at the equation (J for break energy, h for hours):

J = -0.002h + 14

Based on that, a break energy of 0 Joule will be reached after 7056 hours or 294 days.

If you roam around internet forums on 3D printing, you'll find that that value is in the ballpark of people's experiences. I remember one case, where someone put out a piece of ABS in the sun and it broke down after a year.

Tiganis; Burn: The Effects of Heat Aging on Acrylonitrile-Butadiene-Styrene (ABS) Blends. In: Lacasse; Vanier (1999): Durability of Building Materials and Components 8, pp. 912-922.

Answer 2

I would recommend Taulman Bluprint, which has a T_g of 100 °C and prints around 250 °C.

I got a small sample and it printed well with the recommended settings. I didn't do any thermal testing with my print (I made a knob for a lawn mower with it) but Taulman has a solid reputation for engineered filaments.

Answer 3

Your ABS filament is likely to be different than the ABS the paper is talking about, at the minimum the filament has added coloring (ABS is not naturally white), its possible it has other additives to make it easier to extrude and - especially for low cost ABS - it's also possible it has other random contaminant.

The "same" material from different manufacturers is often very obviously different (for low cost filament, different batches from the same manufacturer are sometimes different) so, even if someone here did have experience with cooking ABS for a year, you can never be sure your ABS will work the same as their ABS.

If the information is not in the material data sheet you can try to contact the manufacturer, other then that, you really have no way of knowing other then trying for yourself.

Answer 4

heat it up see what happens also take into consideration additional support in case it degrades its still holding up. if possible give it somekind of protective coat. someone said paint but can you add a coat of resin or ceramic?