The book "Soyuz: A Universal Spacecraft" by Rex Hall, David Shayler (2003) has the text on page 41:
Propulsion Module, ... Descent module, ... Orbital Module... materials used in the fabrication of these modules .... an aluminium alloy was finally chosen. The thermal insulation covering the modules consists of two layers - the upper layer consisting of an asbestos-cloth laminate, and the lower layer of 'a light, heat-insulating material'.
"Leaving Earth: Space Stations, Rival Superpowers, and the Quest for Interplanetary Travel" by Robert Zimmerman (2003) says at page 280:
Protecting Soyuz-TM's bell-shaped descent module were eight blankets of insulation material, each made of many layers of golden foil and an outer micrometeoroid layer.
(note, "golden foil" may describe polymer film, covered by thin layer of any metal)
There were several EVAs to fix some equipment under "vacuum-screen thermal insulation" (EVTI), like by Titov and Monarov (30.06.1988, 20.10.1988, page 254 of Leaving Earth) fixing X-ray telescope TTM "Roentgen" on Kvant-1 (Mir Space station). Or EVA on ISS by Expedition 17 (10-11.07.2008; Orlan spacewalk EVA-20A)