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I am constantly stunned by how few people use keyboard shortcuts, because I've always felt that people who have internalized a core set realize a significant productivity boost.
- How do I get better at recognizing which of my own activities are best done via keyboard shortcuts
- How can I train myself to use them and make them unconscious habits?
- How can I replace frequently used actions by keyboard shortcuts (probably a combination of good resources for looking up existing shortcuts and tools to create my own).
Update: I've significantly updated the focus of the question based on some excellent advice posted to meta.

7Not a real question imho but a discussion topic... Unless this is a community wiki of shortcuts but then it is still too broad since there are different OSes, different applications etc. – Dmitry Selitskiy – 2011-07-26T07:08:13.667
@AdamWuerl: I think it's worth combining the shortcut keys into one post; a lot of the less up-voted posts here are marked as low quality by the system and aren't really salvageable on their own... – Tom Wijsman – 2011-08-23T11:15:10.467